This report summarizes data acquired from 1990 to 1994 for
the gas-hydrate portion of the USGS project "Permafrost
and gas hydrate as possible sources of methane" of the
USGS Global Change and Climate History program. The
objective of this project has been to test the hypothesis
that gas hydrate deposits of the Beaufort Sea continental
shelf are destabilized by the ~10°C temperature increase
that has resulted from the Holocene transgression of the
Arctic Ocean. To test this idea we have selected an area
off the north coast of Alaska centered on Harrison Bay. We
have measured the concentration of methane in surficial
sediments, in the water column when ice is present and
absent, and in seasonal sea ice. Our results show that
more methane is present in the water when ice is present
than when ice is absent, and that methane is also present
within the ice itself, often at higher concentrations than
in the water. Thus the Beaufort Sea shelf of Alaska is a
seasonal source of methane. The primary source of this
methane has not yet been defined, but gas hydrate is a
reasonable candidate.
Purpose:
The objective of this project has been to test the
hypothesis that gas hydrate deposits of the Beaufort Sea
continental shelf are destabilized by the ~10°C
temperature increase that has resulted from the Holocene
transgression of the Arctic Ocean.
Time_Period_of_Content:
Time_Period_Information:
Range_of_Dates/Times:
Beginning_Date: 19920501
Ending_Date: 19940826
Currentness_Reference:
The surveys were undertaken during the last week of April
and first week of May 1992, the middle of April 1993, the
latter portion of April 1994, the second week of September
1993, and the later portion of August 1994.
Status:
Progress: Complete
Maintenance_and_Update_Frequency: As needed
Spatial_Domain:
Bounding_Coordinates:
West_Bounding_Coordinate: -152.20717
East_Bounding_Coordinate: -144.99833
North_Bounding_Coordinate: 72.64800
South_Bounding_Coordinate: 70.05267
Keywords:
Theme:
Theme_Keyword_Thesaurus: none
Theme_Keyword: methane
Theme_Keyword: gas hydrate
Theme_Keyword: petroleum
Theme_Keyword: sea ice
Theme_Keyword: sea water
Place:
Place_Keyword_Thesaurus: None
Place_Keyword: Beaufort Sea
Place_Keyword: Alaska
Place_Keyword: AK
Theme:
Theme_Keyword_Thesaurus: National Geologic Map Database Catalog themes, augmented
Theme_Keyword: 1300 - Marine Geology
Theme_Keyword: 1900 - Geochemistry
Theme:
Theme_Keyword_Thesaurus: ISO 19115 Topic Categories
Theme_Keyword: geoscientificInformation
Place:
Place_Keyword_Thesaurus: Augmented FIPS 10-4 and FIPS 6-4, version 1.0
Place_Keyword: 02185 = North Slope
Place_Keyword: OC10 = Arctic
Access_Constraints: none
Use_Constraints: none
Point_of_Contact:
Contact_Information:
Contact_Person_Primary:
Contact_Person: Thomas D. Lorenson
Contact_Organization: Branch of Pacific Marine Geology
Contact_Address:
Address_Type: mailing address
Address:
Mail Stop 999
U.S. Geological Survey
345 Middlefield Road
The study area showing six north-south transects with the
water and ice station locations.
Browse_Graphic_File_Type: GIF
Data_Set_Credit:
The project has been conducted in collaboration with the
University of Washington and the University of Hawaii. We
thank (1) M.D. Lilley, E.J. Olson, and E. McLaughlin, School
of Oceanography, University of Washington, for the information
on methane concentrations, methane oxidation rates, and
nutrient concentrations in seawater; (2) B.N. Popp, F. J.
Sansone, and T. Rust, SOEST, University of Hawaii, for the
isotopic analyses of methane. We are grateful to (1) P.W.
Barnes, U.S. Geological Survey, for guidence in Arctic
operations, and (2) E. Reimnitz for help in collecting
sediment samples for gas analyses. This work is supported by
the USGS Global Change and Climate History Program.
Native_Data_Set_Environment: Macintosh
Data_Quality_Information:
Attribute_Accuracy:
Attribute_Accuracy_Report:
See process descriptions for analytical methods. For more
information about attribute accuracy, users are urged to
contact the authors.
Logical_Consistency_Report:
CTD (conductivity, temperature, depth) casts were made at each
station. CTD data was recorded internally by a Seacat 19 CTD
probe made by Sea Bird of Seattle Washington. The data was
downloaded onto a computer where it was processed using
Seasoft Version 4.016. The sub-programs LOOPEDIT, BINAVE, then
DERIVE were utilized to process the raw data. The data were
averaged into 0.5m intervals. The upcast and downcast were
evaluated, and only one cast is plotted. In general the upcast
was used because the sensors showed less fluctuation.
Completeness_Report:
Methane oxidation rate is given only for samples collected in
1992 and 1993. Isotopic compositions are given only for
samples collected in 1994. Nutrients are given only for
samples collected in 1992.
Lineage:
Process_Step:
Process_Description:
Measurements of sea water.
In our survey, we measured methane concentration in
sea water under the ice on six primary transects from
nearshore to the shelf break at water depths ranging
from 2.5 to 88m from Cape Halkett east to Mikkelsen
Bay, Alaska. Other surface water samples were taken at
various locations where water depths ranged from 2 to
20m within the area between Camden Bay and the
Colville River Delta. One oceanic surface water sample
was also collected in April 1993 at 72° 38' N.
latitude . The surveys were undertaken during the last
week of April and first week of May 1992, the middle
of April 1993, the latter portion of April 1994, the
second week of September 1993, and the later portion
of August 1994. At each station in April and May, a 23-
cm diameter hole was drilled through the 2-m thick
first-year ice. Niskin bottles (1.7 l) were attached
at intervals to a line lowered to the seafloor and
subsequently tripped to collect water samples for
methane determinations. In September 1993 and August
1994, when no ice was present, a boat was used to
transit to stations. As each Niskin bottle was
recovered, 100 cm3 of water was transferred to a 140
cm3 syringe. A heat lamp to prevent the water from
freezing during April and May surveys. In the
laboratory at the end of each day's field work, 40 cm3
of ultra-pure nitrogen were added to each of the
syringes, and methane was extracted from the water
into the nitrogen at room temperature by shaking the
syringe, following a method modified from McAullife
(1971). A portion of the resulting gas mixture was
measured for methane content by gas chromatography.
Multiple extractions were used on several samples to
determine an empirical extraction efficiency
coefficient which was utilized with the remainder of
the samples that were extracted only once. Our
analyzed gas standard contained 10 ppm ±2% methane in
nitrogen. Duplicate samples were analyzed for each
water depth with an average standard deviation
of ±0.6nM.
CTD (conductivity, temperature, depth) casts were made
at each station. CTD data was recorded internally by a
Seacat 19 CTD probe made by Sea Bird of Seattle
Washington. The data was downloaded onto a computer
where it was processed using Seasoft Version 4.016.
The sub-programs LOOPEDIT, BINAVE, then DERIVE were
utilized to process the raw data. The data were
averaged into 0.5m intervals. The upcast and downcast
were evaluated, and only one cast is plotted. In
general the upcast was used because the sensors showed
less fluctuation.
The methods utilized to measure nutrients in this
study were adapted from older colorimetric procedures
and are described in detail by Whitledge and others,
(1981). A basic description of each method, conducted
on a Technicon Autoanalyzer System, follows.
Phosphate is determined as phosphomolybdic acid which
in its reduced form in the presence of antimony has an
absorption maximum at 880 nm. The method is basically
an automated version of the procedure of Murphy and
Riley (1962).
Orthosilicic acid is determined by its reaction with
molybdate in aqueous acidic solution to form
silicomolybdic acid. In this procedure, which is
basically that of Armstrong and others, (1967),
stannous chloride is used to reduce silicomolybdic
acid to the heteropolic acid which has an absorption
maximum at 820 nm.
Nitrite is determined by the Greiss reaction in which
sulfanilamide and N-(1-Napthyl)ethylenediamine
dihydrochloride react with nitrite in aqueous acidic
solution to form an intensely pink diazo dye with an
absorption maximum at 540 nm (Bendschneider and
Robinson, 1952). Nitrate, after it is reduced to
nitrite by passage through a column of copperized
cadmium filings, is determined in an identical manner
to nitrite (Wood and others 1967). This analysis gives
the sum of nitrate + nitrite, and nitrate is
determined by difference.
Ammonium is determined by the Berthelot reaction in
which hypochlorous acid and phenol react with ammonium
in aqueous alkaline solution to form indophenol blue,
an intensely blue chromophore with an absorption
maximum at 637 nm. The method utilized is a
modification of the procedure reported by Slawyk and
MacIsaac (1972).
Process_Date: 1994
Process_Step:
Process_Description:
Measurements of sea ice.
The methane content of sea ice was measured at 51
stations in 1993 and 1994. A 1m long by 7.6 cm
diameter ice corer with an extension was used to core
through the ice to sea water. The ice core was laid
out on the sea ice, measured and cut into 10 cm
sections. Selected intervals were chosen, then placed
in 1-liter friction sealed cans equipped with 2 septa
ports, sealed, and kept frozen. At the field
laboratory, each sample was weighed, then the
headspace within the can was purged with ultra pure
nitrogen for 5 minutes at flow rates exceeding 200
ml/min. Tests on the methane content of the purged
headspace with the frozen ice core inside yielded
concentrations less than 0.1 ppm. The cans containing
ice samples were placed in hot water baths and
stabilized at approximately 20°C. Each can was shaken
by hand for about 30 seconds to partition the
dissolved methane between the water and the nitrogen
headspace. Next, a syringe containing 30 ml of ultra
pure grade nitrogen was injected into the can, then 30
ml of the resulting mixture of headspace and gas was
removed and analyzed for methane content in the same
manner as described for sea water samples. The volume
of headspace in the can was determined by the weight
of the ice sample, assuming that once melted the water
occupied a volume of 1 ml/gm.
Process_Date: 1994
Process_Step:
Process_Description:
Measurements of sea-floor sediment.
Sediment samples were taken in May 1992 operating from
the ice canopy. A hole was augured in the ice, through
which a 45 x 7.5 cm core barrel with an auger cutting
head was lowered. The core barrel was attached to
1.5-m long connecting stems in series up to a maximum
length of 15.5 m. Once on the ocean bottom, the core
barrel was rotated by hand with the aid of a T-bar
until no further penetration was achieved. Upon
retrieval, the liner containing sediment was extruded
onto the ice. The least disturbed 10-cm long (a volume
of about 450 ml wet sediment) section of the core was
chosen and placed in a septa-equipped 1-liter sample
can. Seawater was added to the brim of the can, then
200 ml of water was removed, creating a 200 ml
headspace. About 2-3 grams of sodium azide was added
as a biocide. The can was sealed, then purged with
helium at a flow rate estimated to be greater then 300
ml/min for 5 minutes. The samples were kept frozen
until analysis at our Menlo Park laboratories.
Process_Date: 199205
Process_Step:
Process_Description:
Measurements of methane isotopic composition.
A limited number of measurements of the carbon
isotopic composition of methane were made at the
University of Hawaii. The results reveal a wide range
of values from -31.1 to -80.5 o/oo.
Process_Date: 1995
Process_Contact:
Contact_Information:
Contact_Person_Primary:
Contact_Person: Brian N. Popp
Contact_Address:
Address_Type: mailing address
Address:
2525 Correa Road, HIG 415
University of Hawai`i-Manoa
Identifier for the sample locality, composed as
YYMsssR where YY is the last two digits of the year,
M is the month (no samples were taken from October
through December, thus one digit suffices), sss is the
site number, and R (literally) is present to indicate
that the site was occupied at an earlier date.
Attribute_Definition_Source: USGS OFR 95-70
Attribute:
Attribute_Label: Latitude
Attribute_Definition: North latitude of the sample locality.
Attribute_Definition_Source: FIPS 70-1
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0
Range_Domain_Maximum: 90
Attribute_Units_of_Measure: decimal degrees
Attribute_Measurement_Resolution: 0.00016667
Attribute:
Attribute_Label: Longitude
Attribute_Definition:
Longitude of the sample locality. Negative values are
measured westward from the Prime Meridian, positive
values are measured eastward from the Prime Meridian.
Attribute_Definition_Source: FIPS 70-1
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0
Range_Domain_Maximum: 180
Attribute_Units_of_Measure: decimal degrees
Attribute_Measurement_Resolution: 0.00016667
Attribute:
Attribute_Label: Date
Attribute_Definition:
Calendar date when sample was collected, expressed as
a FIPS date using the form YYYYMMDD where YYYY
signifies the year, MM the month, and DD the day
(month and day beginning with 1).
Attribute_Definition_Source: FIPS 4-1
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 19920501
Range_Domain_Maximum: 19940824
Attribute_Units_of_Measure: Calendar days
Attribute_Measurement_Resolution: 1
Attribute:
Attribute_Label: Sample depth (m)
Attribute_Definition:
Depth in meters at which water was sampled,
measured from sea-surface.
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0
Range_Domain_Maximum: 88
Attribute_Units_of_Measure: meters
Attribute_Measurement_Resolution: 0.5
Attribute:
Attribute_Label: Methane (nM)
Attribute_Definition: Dissolved methane concentration in the water.
Carbon isotopic composition (delta-13C) relative
to PDB
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: -80.5
Range_Domain_Maximum: -31.1
Attribute_Units_of_Measure: Parts per thousand by weight
Attribute_Measurement_Resolution: 0.1
Attribute:
Attribute_Label: Methane Specific Oxidation
Attribute_Definition:
Rate of microbial oxidation of methane.
This "specific oxidation rate" is really just the
first order rate constant for methane uptake and has
the units (1/day) because the oxidation rate (nM/day)
is divided by the concentration (nM).
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: 1/day
Attribute:
Attribute_Label: Methane Oxidation Rate (nM/day)
Attribute_Definition:
The first order rate constant for the microbial
oxidation of methane.
We measure methane oxidation by first removing (via
shaking) most of the methane from the collected
samples. We then spike the samples with a known
amount of labeled methane which is somewhere near the
concentration of methane in the natural sample. We
measure the rate of methane oxidation by watching
labeled carbon dioxide grow in. Some methane is
converted to biomass and we get at this part by
filtering and counting the amount of labeled
particulate carbon.
Once we have these numbers, we calculate what is
called the "specific oxidation rate". This is simply
the measured rate divided by the concentration of
methane in the incubation vials. This "specific
oxidation rate" is really just the first order rate
constant for methane uptake and has the units (1/day)
because the oxidation rate (nM/day) is divided by the
concentration (nM).
We can then derive what we call the "ambient oxidation
rate" by multipling the "specific oxidation rate" by
the concentration of methane actually measured in the
samples. This obviously only works if first order
kinetics are followed but we have found this to be the
case in all of the environments we have studied.
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: nM per day
Attribute:
Attribute_Label: Comments
Attribute_Definition:
Descriptive information about the water samples
or the analyses of them.
Attribute_Definition_Source: USGS OFR 95-70
Attribute:
Attribute_Label: PO4
Attribute_Definition: Phosphate concentration in water samples.
Attribute_Definition_Source:
Phosphate is determined as phosphomolybdic acid which
in its reduced form in the presence of antimony has an
absorption maximum at 880 nm.
The method is basically an automated version of the
procedure of Murphy and Riley (1962).
Attribute:
Attribute_Label: Si
Attribute_Definition: Silica concentration in water sample.
Attribute_Definition_Source:
Orthosilicic acid is determined by its reaction with
molybdate in aqueous acidic solution to form
silicomolybdic acid.
In this procedure, which is basically that of
Armstrong and others, (1967), stannous chloride is
used to reduce silicomolybdic acid to the heteropolic
acid which has an absorption maximum at 820 nm.
Attribute:
Attribute_Label: NO3
Attribute_Definition: Nitrate concentration in water samples.
Attribute_Definition_Source:
Nitrate, after it is reduced to nitrite by passage
through a column of copperized cadmium filings, is
determined in an identical manner to nitrite (Wood and
others 1967). This analysis gives the sum of nitrate +
nitrite, and nitrate is determined by difference.
Attribute:
Attribute_Label: NO2
Attribute_Definition_Source:
Nitrite is determined by the Greiss reaction in which
sulfanilamide and N-(1-Napthyl)ethylenediamine
dihydrochloride react with nitrite in aqueous acidic
solution to form an intensely pink diazo dye with an
absorption maximum at 540 nm (Bendschneider and
Robinson, 1952).
Attribute:
Attribute_Label: NH4
Attribute_Definition: Ammonium concentration in water samples.
Attribute_Definition_Source:
Ammonium is determined by the Berthelot reaction in
which hypochlorous acid and phenol react with ammonium
in aqueous alkaline solution to form indophenol blue,
an intensely blue chromophore with an absorption
maximum at 637 nm. The method utilized is a
modification of the procedure reported by Slawyk and
MacIsaac (1972).
Detailed_Description:
Entity_Type:
Entity_Type_Label: CTD cast
Entity_Type_Definition_Source: USGS OFR 95-70
Attribute:
Attribute_Label: Temperature
Attribute_Definition: In situ water temperature.
Attribute_Definition_Source:
CTD (conductivity, temperature, depth) casts were made
at each station. CTD data was recorded internally by a
Seacat 19 CTD probe made by Sea Bird of Seattle
Washington. The data was downloaded onto a computer
where it was processed using Seasoft Version 4.016.
The sub-programs LOOPEDIT, BINAVE, then DERIVE were
utilized to process the raw data.
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: degrees Celsius
Attribute:
Attribute_Label: Salinity
Attribute_Definition:
Salinity of the water as determined from the
conductivity measurements recorded by the CTD
instrument.
Attribute_Definition_Source:
CTD (conductivity, temperature, depth) casts were made
at each station. CTD data was recorded internally by a
Seacat 19 CTD probe made by Sea Bird of Seattle
Washington. The data was downloaded onto a computer
where it was processed using Seasoft Version 4.016.
The sub-programs LOOPEDIT, BINAVE, then DERIVE were
utilized to process the raw data.
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: Parts per thousand by weight
Attribute:
Attribute_Label: Depth
Attribute_Definition:
Depth of the CTD instrument when temperature and
conductivity were recorded. This parameter is
derived internally by the CTD instrument by using
ambient hydrostatic pressure.
Attribute_Definition_Source:
CTD (conductivity, temperature, depth) casts were made
at each station. CTD data was recorded internally by a
Seacat 19 CTD probe made by Sea Bird of Seattle
Washington. The data was downloaded onto a computer
where it was processed using Seasoft Version 4.016.
The sub-programs LOOPEDIT, BINAVE, then DERIVE were
utilized to process the raw data.
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: meters
Attribute:
Attribute_Label: Conductivity
Attribute_Definition:
Conductivity of water as determined by the CTD
instrument.
Attribute_Definition_Source:
CTD (conductivity, temperature, depth) casts were made
at each station. CTD data was recorded internally by a
Seacat 19 CTD probe made by Sea Bird of Seattle
Washington. The data was downloaded onto a computer
where it was processed using Seasoft Version 4.016.
The sub-programs LOOPEDIT, BINAVE, then DERIVE were
utilized to process the raw data.
Detailed_Description:
Entity_Type:
Entity_Type_Label: ice sample
Entity_Type_Definition_Source: USGS OFR 95-70
Attribute:
Attribute_Label: Core interval (cm)
Attribute_Definition:
The length of the part of the ice core that was
analyzed.
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: centimeters
Attribute:
Attribute_Label: Can Wt. gm
Attribute_Definition:
Weight in grams of the container before placing
the sample into it.
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: grams
Attribute:
Attribute_Label: Can+sample Wt. gm
Attribute_Definition: Weight in grams of the sample with the container.
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: grams
Attribute:
Attribute_Label: Sample Wt. gm
Attribute_Definition:
Difference between variable "Can+sample Wt. gm"
and variable "Can Wt. gm".
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: grams
Attribute:
Attribute_Label: Headspace Liters
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: liters
Attribute:
Attribute_Label: Methane ppm
Attribute_Definition:
Concentration of methane in the ice-core sample,
as a proportion of the weight of the sample.
Attribute_Definition_Source: USGS OFR 95-70
Attribute_Domain_Values:
Range_Domain:
Attribute_Units_of_Measure: pars per million by weight
Attribute:
Attribute_Label: Methane (nM)
Attribute_Definition:
Concentration of methane in the ice-core sample,
in absolute rather than relative terms.
Resource_Description: U.S. Geological Survey Open-File Report 95-70
Distribution_Liability:
This report is preliminary and has not been reviewed for
conformity with U.S. Geological Survey editorial standards (or
with the North American Stratigraphic Code). Any use of trade,
product, or firm names is for descriptive purposes only and does
not imply endorsement by the U.S. Government.
Standard_Order_Process:
Digital_Form:
Digital_Transfer_Information:
Format_Name: TEXT
Format_Specification: tab-delimited
Format_Information_Content: Gas hydrate station data
Metadata_Standard_Name: Content Standard for Digital Geospatial Metadata
Metadata_Standard_Version: FGDC-STD-001-1998
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